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ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED ALKENES USING CHIRAL 2-SULFONYLOXAZIRIDINES - EVIDENCE FOR A... OF 2-SULFONYLOXAZIRIDINES AND 2-SULFAMYLOXAZIRIDINES USING POTASSIUM PEROXYMONOSULFATE (OXONE)
3-Chloroperoxybenzoic acid, MCPBA, meta-Chloroperbenzoic acid
... peracids, such as peracetic acid or on potassium peroxymonosulfate (Oxone)... the methylation of a phenol derivative with dimethyl sulfate and to the m -CPBA-induced epoxidation...
Cathleen Crudden
Crudden, Cathleen M.; Matsuhashi, Hayao. Catalytic Epoxidation of Alkenes with Oxone. 2. Fluoro Ketones. Journal of Organic Chemistry (1997), 62 (24), 8288-8289.
Selective Reactions of Alkenes
The most general procedure for catalytic enantioselective epoxidation is that developed by Yian Shi of Colorado State University, using the Oxone-generated dioxiranes from 7 and 8
Publications page 7
246: Enantioselective epoxidation of 2,2-dialkyl-2H chromenes with oxone and jacobsen (S,S) Mn(III) (Ph-Salen) CI-Complex: Solvent effect: A.V.RamaRao, M.K.Gujar, B.V.N.B.Sharma: Ind..J...
C&EN: COVERSTORY -CHIRAL CHEMISTRY
AN ALTERNATIVE ROUTE to single-enantiomer chiral epoxides is asymmetric epoxidation of olefins... the original methodology, in which the oxidant is potassium peroxomonosulfate (Oxone...
CV of Prof. D. Yang
In Situ Catalytic Epoxidation of Olefins with Tetrahydrothiopyran-4-one and Oxone: 2-Methyl-2,3-Diphenyloxirane. Org. Syn. 2001 , 78 , 225-233. M.-K.
Prof. D. Yang
We developed a mild and general method for epoxidation of olefins using dioxiranes generated in situ from ketones and Oxone. We also developed chiral ketone catalysts for highly...
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Epoxidation (oxone "green" vs MCPBA) - successfully converted ; a ; Electrophilic Substitution; a; Limonene Extraction (Liquid CO2 "green" vs methylene chloride or something similar) - successfully converted...
